Disney villains who are 20 years old or older. In non-human cases, characters who are fully grown or developed.
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- Babydoll Beagle
- Barnaby (Babes in Toyland)
- Beard Deer
- Beatrice Le Beak
- Beatrice Stanhope
- Beauty Smith
- Beetle
- Behemoth
- Behemoth (Muppets)
- Behrang
- Bella
- Belle's sisters
- Belle's suitors
- Ben and Lon
- Bennett
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- Bering
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- Bernadette the Chicken
- Bernice
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- Big Ben
- Big Cheese
- Big Daddy-O Cool
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- Bill Bluff
- Bill Fisk
- Bill Sikes
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- Billy the Squid
- Bing-Bong
- Bingo
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- Bizarrah
- Black Dog
- Black Fairy
- Black Heron
- Black Mariah
- Black Powder
- Black Scorpions
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- Blackfin
- Blackout
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- Bleed
- Blight
- Blind Ivan
- Blind Witch
- Blite
- Blizzard
- Blobzilla
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- Bloodbottler
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- Blue Grit
- Blue Tornado
- Bluto
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- Bob
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- Boltz
- Bone Spider
- Bonecruncher
- Boogie Men
- Bookman
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- Boom-Boom Beagle
- Boopy Von Ha-Ha Pants
- Boreas (Fantasia)
- Borg Guillarson
- Boss Beaver
- Boss Ember
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- Bossk
- Boston Terroriers
- Boswell
- Bouffant Beagle
- Bowler Hat Guy
- Br'er Bear
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- Br'er Fox
- Brace Channing
- Brahl
- Brain Sponge
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- Bread Baron
- Breathless Mahoney
- Brenda
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- Brian Hayward
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- Bride of Nine Spiders
- Bridget
- Briggs
- Brimstone
- Brom Titus
- Brother Herman the Evil Ant
- Brun
- Bruno Von Beak
- Bruno von Stickle
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- Brutale Drake
- Bubba
- Bubbha
- Bubbles
- Buck Buckerson
- Bud (Chip 'n Dale)
- Bud Gleeful
- Buffy and Muffy Vanderschmere
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- Bugs (Winnie the Pooh)
- Buldeo
- Buldeo (Jungle Book 1994)
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- Bum Bum Ghigno
- Bunny Wiles
- Bushmaster
- Butcherboy
- Butler
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- C.C.
- Cabbie
- Cad Bane
- Caldwell
- Calico (Muppets)
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- Calliope
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- Calvin Chadwick
- Calvin Zabo
- Candace Montana
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- Captain (Lab Rats)
- Captain Anderson
- Captain Bill Fawcett
- Captain Bloodbeard
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- Captain Gore
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- Captain Jay Fuller
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- Captain of the Guard
- Captain Peg-Hook
- Captain Phasma
- Captain Rochefort
- Captain Salazar
- Captain Storm
- Captain Wraith
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- Carl Hoffman
- Carl Karl's evil robots
- Carl the Evil Cockroach Wizard
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- Carlo Mancini
- Carnage
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- Castor
- Catastrophe
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- Caterpillar (Once Upon a Time)
- Catfish Booray
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- Catter Cadaver
- Cattlemen
- Celestabellebethabelle
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- Cement Head
- Cerebella
- Chacha
- Chakashi
- Chameleon
- Chameleon (Marvel)
- Chan Ho Yin
- Chancellor Esteban
- Chancellor Goodwin